Optimization and Calculation of TbCl3-ACl（A = Li, Na, K, Rb, Cs）Phase Diagrams
摘要
By using CALPHAD (Calculation of Phase Diagram) technique the optimization and calculation of the binary systems of TbCl3-ACl (A= Li, Na, K, Rb, Cs) were carried out. For describing the Gibbs free energy of liquid phase in these systems the new modified quasichemical model in the pair-approximation for short-range ordering was used. From measured phase equilibria data and experimental integral properties the TbCl3-ACl phase diagrams were optimized and calculated. A set of thermodynamic functions was optimized based on an interactive computer-assisted analysis. The calculated phase diagrams and thermodynamic data are self-consistent.
引用本文（GB/T 7714）
孙益民, Jing Zhang, 关明云, 等. Optimization and Calculation of TbCl3-ACl（A = Li, Na, K, Rb, Cs）Phase Diagrams[J]. Acta Scientiarum Naturalium Universitatis Sunyatseni, 2005.
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