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A Novel Catalyst for Liquid Phase Hydrogenation of m-Dinitrobenzene to m-Phenylenediamine

YingXinLIUZuoJunWEIJiXiangCHENJiYanZHANGXinXueLIXiongHuiWEI

2005中国化学快报:英文版Chemistry被引 1

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摘要

A novel lanthana-promoted nickel catalyst supported on silica for the liquid phase hydrogenation of m-dinitrobenzene to m-phenylenediamine was prepared by an incipient wetness sequential impregnation method. It was found that Ni-La/SiO2 catalyst exhibited high activity and stability for m-dinitrobenzene hydrogenation. Over this catalyst, the conversion of m-dinitrobenzene and the yield of m-phenylenediamine were up to 97.1% and 93.5%, respectively,at 373 K and 2.6 MPa hydrogen pressure after reaction for 1 h.

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YingXinLIU, ZuoJunWEI, JiXiangCHEN, 等. A Novel Catalyst for Liquid Phase Hydrogenation of m-Dinitrobenzene to m-Phenylenediamine[J]. 中国化学快报:英文版, 2005.

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