Synthesis and CD Spectra of Chiral Molybdenum-fullerenyl Complexes with Pineno-bipyridine Ligands
摘要
The synthesis and characterization of two chiral fullerene complexes(+)4in^CD-[Mo(η^2-C60)(CO)3(L^RR)]1 and (-)430^CD-[Mo(η^2-C60)(CO3)(L^SS)2 were described,the CD spectra of 1 and 2 in the visible range show Cotton effects,which are approximately of mirror image,indicating that the appended pineno-groups with opposite chirality in bipyridines can perturb the fullcrene chromophores through the molybdenum centers and lead to induced CD effects.
引用本文（GB/T 7714）
HuiZHANG, CaiFeiZHU, Li-Li Li-Li, 等. Synthesis and CD Spectra of Chiral Molybdenum-fullerenyl Complexes with Pineno-bipyridine Ligands[J]. 中国化学快报：英文版, 2004.
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