Activation of Carbon Dioxide and Synthesis of Propylene Carbonate
摘要
Cycloaddition of carbon dioxide and propylene oxide to propylene carbonate catalyzed by tetra-tert-butyl metal phthalocyanine in the presence of tributylamine (TBA) shows higher yield than catalyzed by unsubstituted metal phthalocyanine. Comparing different catalysts of diverse metals, (t-Bu)4PcMg is more active than (t-Bu)4PcFe. But (t-Bu)4PcCo and (t-Bu)4PcNi only have low catalytic activities towards the reaction. Moreover, the yield will increase as the temperature increases.
引用本文（GB/T 7714）
YingJuZHANG, YueEFENG. Activation of Carbon Dioxide and Synthesis of Propylene Carbonate[J]. 中国化学快报：英文版, 2002.
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