Microstructure and Thermal Properties of （ 1 - x ） As2S3- x CdCl2 Glassy System
摘要
The homogeneous glass samples of the (1-x)As2S3-xCdCl2 where x=0 and 0.05 were prepared by the conventional melt-quenched method.The addition of 5mol% CdCl2 enhanced the glass transition temperature of pure As2S3 glass sample by about 30℃.Based on the experimental data,the microstructure is considered to be that the discrete molecule species of AsCl3 and nanocrystal CdS is homogeneously dispersed in the disordered polymer network formed by AsS3 pyramids interconnected by sulfur bridges.
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TAOHai-zheng, ZHAOXiu-jian, JINGCheng-bin, 等. Microstructure and Thermal Properties of （ 1 - x ） As2S3- x CdCl2 Glassy System[J]. Acta Scientiarum Naturalium Universitatis Sunyatseni, 2003.
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