Two New C21 Steroids from Marsdenia tenacissima
摘要
Two new C21 steroids were isolated from the CHCl3 extract of the stem of Marsdenia tenacissima. On the basis of spectroscopic analysis and chemical methods, their structures were elucidated as 17β-tenacigenin B (2) and 3-O-6-deoxy-3-O-methyl-β-D-allopyranosyl-(1→4)-β-D-oleandropyranosyl-tenacigenin C (3). The structure of the known aglycon tenacigenin C was revised as 5α, 9α, 17β-pregnane-3β, 8β, 11α, 12β, 14β-pentanol-20-one. Compound 3 is the fust reported glycoside of tenacigenin C.
引用本文(GB/T 7714)
JunDENG, ZhiXinLIAO, DaoFengCHEN. Two New C21 Steroids from Marsdenia tenacissima[J]. 中国化学快报:英文版, 2005.
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