Preparation and Crystal Structure of Sarcosine 5-Nitrosalicylic Acid Organic Adduct
摘要
The title compound (C10H12N2O7, Mr = 272.22) crystallizes in triclinic, space group P with a = 5.532(2), b = 9.760(4), c = 11.731(5) A, α = 68.107(7), β = 89.179(7), γ = 77.830(7)o, V = 573.1(4) A3, Z = 2, Dc = 1.578 g/cm3, F(000) = 284 and μ(MoKa) = 0.136 mm-1. The final R = 0.0400 and wR = 0.0951 for 1468 observed reflections with I > 2σ(I). The title compound is a 1:1 adduct of sarcosine and 5-nitrosalicylic acid. The nitrogen atom of sarcosine is protonated, and the proton is from the carboxyl group of sarcosine and 5-nitrosalicylic acid with the probability of 50 percent for each. The 5-nitrosalicylic acid and sarcosine molecule of the title adduct are ABAB arranged along the c axis. There exist a lot of hydrogen bonds in the structure, linking sarcosine and 5-nitrosalicylic acid to form a three-dimensional network.