Cyclic Oligomers of Phenolphthalein Polyarylene Ether Sulfone (Ketone): Preparation Through Cyclo-depolymerisation of Corresponding Polymers
摘要
Cyclic oligomers of phenolphthalein polyarylene ether sulfone(ketone) were preparedthrough cyclo-depolymerisation of corresponding polymers using CsF as the catalyst in dipolaraprotic solvent DMAc and DMF, and a family of macrocycles containing from dimer up to at leastheptamer were confirmed by GPC, HPLC and MALDI-TOF-MS. The yields of cyclics get ashigh as 86.3% and 87.9% respectively.
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HongHuaWANG, JinYingDING, TianLuCHEN. Cyclic Oligomers of Phenolphthalein Polyarylene Ether Sulfone (Ketone): Preparation Through Cyclo-depolymerisation of Corresponding Polymers[J]. 中国化学快报:英文版, 2004.
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