Synthesis and Crystal Structure of One－dimensional Chain Complexes [K （18－C－6） ]2[M （mnt）2] （M=Zn, Hg）

WANGDa-qi、HEGuo-fang、QIULin-lin、DOUJian-min

2003Acta Scientiarum Naturalium Universitatis SunyatseniMaterials Science被引 1

摘要

The reactions of 18-crown-6 with each of K2[M(mnt)2](M=Zn, Hg; mnt=1,2-dicyanoethene-1,2-dithiolate, C2S2(CN)2-2) were studied and novel complexes [K(18-C-6)]2[Zn(mnt)2](1) and [K(18-C-6)]2[Hg(mnt)2](2) were characterized by elemental analysis, IR spectrum and X-ray diffraction analysis. Complex 1 displays a one-dimensional chain of [K(18-C-6)]2[Zn(mnt)2] bridged by K-O interactions between adjacent [K(18-C-6)]+ units. Complex 2 is also a one-dimensional chain of [K(18-C-6)]2[Hg(mnt)2] bridged by K...S weak interactions between adjacent [K(18-C-6)]+ and [Hg(mnt)2]2-.

引用本文（GB/T 7714）

WANGDa-qi, HEGuo-fang, QIULin-lin, 等. Synthesis and Crystal Structure of One－dimensional Chain Complexes [K （18－C－6） ]2[M （mnt）2] （M=Zn, Hg）[J]. Acta Scientiarum Naturalium Universitatis Sunyatseni, 2003.

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