Partial oxidation of methane to syngas in tubular oxygen-permeable reactor
摘要
A dense Ba0.5Sr0.5Co0.8Fe0.2O3-δ membrane tube was prepared by the extruding method. Furthermore, a membrane reactor with this tubular membrane was successfully applied to partial oxidation of methane (POM) reaction, in which the separation of oxygen from air and the partial oxidation of methane are integrated in one process. At 875°C, 94% of methane conversion, 98% of CO selectivity, 95% of H2 selectivity, and as high as 8.8 mL/(min·cm2) of oxygen flux were obtained. In POM reaction condition, the membrane tube shows a very good stability.
引用本文(GB/T 7714)
Wang, Haihui, Cong Cong, 等. Partial oxidation of methane to syngas in tubular oxygen-permeable reactor[J]. 中国科学通报:英文版, 2002.
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