[Stabilization Effects of Fe-Mn Binary Oxide on Arsenic and Heavy Metal Co-contaminated Soils Under Different pH Conditions].
摘要
pH is one of the most important factors affecting speciation and stabilization of arsenic and heavy metals in soil. In this study, Fe-Mn binary oxide (FMBO), synthesized by redox and precipitation reactions, was taken as the research object to evaluate its stabilization effects on As, Pb, Cd, Zn, and Cu in three types of soils under different pH conditions and to study the impacts on soil pH and buffering capacity. The results showed that the leaching concentrations of As and Pb were lower in the pH range of 3-9 (neutral and weak acidic) and 5-10 (neutral and weak alkaline); and Cd, Zn, and Cu were stable in the pH range of 7-11 (alkaline). The stability and stabilization effects of FMBO were better under alkaline conditions than acidic. In the optimal pH range, the optimum stabilization efficiency of FMBO could reach 92.7%, 100%, 97.0%, 88.7%, and 82.7% for As, Pb, Cd, Zn, and Cu, respectively. In addition, FMBO addition could increase soil pH and the acid buffering capacity moderately, which improved heavy metal stabilization and made it more suitable for acid soils and areas with more acid rain. From the correlation of contaminants and soil elements in the leachates, Fe played an important role in As stabilization, and pH had a great influence on the stabilization of Pb, Cd, Zn, and Cu.