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Oxidative Cyclization of Lithium 4-Ethoxy-1,1,1-trifluoro-4-oxobut-2-en-2-olate

N. S. BoltachevaПавел А. СлепухинV. I. FilyakovaValery N. Charushin

2019Russian Journal of Organic ChemistryPharmacology, Toxicology and Pharmaceutics被引 1

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摘要

Diethyl 2,5-dihydroxy-2,5-bis(trifluoromethyl)tetrahydrofuran-3,4-dicarboxylate has been synthesized for the first time by reaction of lithium 4-ethoxy-1,1,1-trifluoro-4-oxobut-2-en-2-olate with manganese(III) acetate. The structure of its (2 S *3 S *4 S *5 S *) stereoisomer has been confirmed by X-ray analysis.

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N. S. Boltacheva, Павел А. Слепухин, V. I. Filyakova, 等. Oxidative Cyclization of Lithium 4-Ethoxy-1,1,1-trifluoro-4-oxobut-2-en-2-olate[J]. Russian Journal of Organic Chemistry, 2019.

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DOI:https://doi.org/10.1134/s1070428019060216

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