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Effect of Cs-Incorporated NiO<sub><i>x</i></sub> on the Performance of Perovskite Solar Cells

Hui‐Seon KimJi‐Youn SeoHaibing XieMónica Lira‐CantúShaik M. ZakeeruddinMichaël GrätzelAnders Hagfeldt

2017ACS OmegaEngineering被引 47开放获取

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摘要

High Resolution Image Download MS PowerPoint Slide The effect of Cs-incorporated NiO x on perovskite solar cells with an inverted structure was investigated, where NiO x and PCBM were used as selective contacts for holes and electrons, respectively. It was found that the generation of an Ni phase in an NiO x layer was significantly suppressed by employing cesium. Furthermore, Cs-incorporated NiO x enabled holes to be efficiently separated at the interface, showing the improved photoluminescent quenching and thus generating higher short-circuit current. The effect of Cs incorporation was also prominent in the inhibition of recombination. The recombination resistance of Cs-incorporated NiO x was noticeably increased by more than three-fold near the maximum power point, leading to a higher fill factor of 0.78 and consequently a higher power conversion efficiency of 17.2% for the device employing Cs-incorporated NiO x .

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Hui‐Seon Kim, Ji‐Youn Seo, Haibing Xie, 等. Effect of Cs-Incorporated NiO<sub><i>x</i></sub> on the Performance of Perovskite Solar Cells[J]. ACS Omega, 2017.

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DOI:https://doi.org/10.1021/acsomega.7b01179

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