素坯密度对气相渗硅制备C/C-SiC复合材料结构与性能的影响
摘要
The 3-D needled C/C preforms with different densities deposited by chemical vapor infiltration (CVI) method were used to fabricate C/C-SiC composites by gaseous silicon infiltration (GSI). The porosity and CVI C thickness of the preforms were studied, and the effects of preform density on the mechanical and thermal properties of C/C-SiC composites were analyzed. The results show that with the increase of preform density, the preform porosity decreases and the CVI C thickness increases from several hundred nanometers to several microns. For the C/C-SiC composites, as the preform density increases, the residual C content increases while the density and residual Si content decreases. The SiC content first keeps at a high level of about 40% (volume fraction), which then quickly reduces. Meanwhile, the mechanical properties increase to the highest values when the preform density is 1.085g/cm<sup>3</sup>, with the flexure strength up to 308.31MP and fracture toughness up to 11.36MPa·m<sup>1/2</sup>, which then decrease as the preform density further increases. The thermal conductivity and CTE of the composites, however, decrease with the increase of preform density. It is found that when the preform porosity is too high, sufficient infiltration channels lead to more residual Si, and thinner CVI C thickness results in the severe corrosion of the reinforcing fibers by Si and lower mechanical properties. When the preform porosity is relatively low, the contents of Si and SiC quickly reduce since the infiltration channels are rapidly blocked, resulting in the formation of large closed pores and not high mechanical properties.