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Kinetics and Mechanism of Exothermic First-stage Decomposition Reaction for 2,6-Dinitro-4,8-bis(2,2,2-trinitroethyl)-2,4,6,8-tetraazabicyclo[3.3. 1]nonane-3,7-dionel

HURong-zuYANGDe-suoZHAOFeng-qiCHENPeiLUOYangCHENSan-pingZHAOHong-anSONGJi-rong

2004Acta Scientiarum Naturalium Universitatis SunyatseniEngineering被引 1

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摘要

Introduction 2,6-Dinitro-4,8-bis(2,2,2-trinitroethyl)-2,4,6,8-tetraazabicyclo[3.3.1] nonane-3,7-dionel is a typical cyclourea nitramine. Its crystal density is 1.94 g/cm3. The detonation velocity corresponding to ρ=1.920 g/cm3 is about 8957 m/s. It has the potential application as high explosive due to the above-mentioned high performance. Its preparation[1], properties[1] and hydrolytic behavior[2] have been reported. In the present paper, we report its kinetic parameters and mechanism of the exothermic first-stage decomposition reaction studied with DSC, TG-DTG and IR.

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HURong-zu, YANGDe-suo, ZHAOFeng-qi, 等. Kinetics and Mechanism of Exothermic First-stage Decomposition Reaction for 2,6-Dinitro-4,8-bis(2,2,2-trinitroethyl)-2,4,6,8-tetraazabicyclo[3.3. 1]nonane-3,7-dionel[J]. Acta Scientiarum Naturalium Universitatis Sunyatseni, 2004.

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