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Syntheses and Crystal Structures of Five Sr II -Ln III (Ln=Nd,Pr,Er) Heterometallic Coordination Polymers

CaoYan-YuanChenYanmeiLiuWeiLiYahong

2013结构化学Chemistry被引 1

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摘要

Five novel SrII-LnIIIheterometallic coordination polymers based on pyridine-2,6-dicarboxylic acid(H2pda)and imidazole(im),namely,[LnSr(pda)3(H2O)5]·Him·C2H5OH·3H2O(Ln=Nd(1);Pr(2)),[Ln2Sr(pda)6(H2O)5]·4Him·C2H5OH·5H2O(Ln=Nd(3);Pr(4)),and[ErSr(pda)3(H2O)4]·Him·3.5H2O(5),have been prepared and structurally characterized.X-ray crystallographic analyses revealed that these complexes display three varieties of 1-D chain structures.Several types of hydrogen bonding interactions are found for 1~5,which connect the1-D chain structures to form 2-D supramolecular networks.

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Cao, Yan-Yuan, Chen, 等. Syntheses and Crystal Structures of Five Sr II -Ln III (Ln=Nd,Pr,Er) Heterometallic Coordination Polymers[J]. 结构化学, 2013.

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