1-D Infinite Array of Metalloporphyrin Cages
摘要
The reaction of Co(II) with 5,15-dipyridyl-10,20-diphenylporphyrin (H(2)DPyP) produces the first metal-organic coordination polymer supported by a trans meso-bifunctional porphyrin ligand. Formulated empirically as [Co(3)(DPyP)(3)] x 4DMF, this compound exhibits a ribbonlike coordination network consisting of tetranuclear metalloporphyrin cages. The DMF guest molecules fill the intra-ribbon cages as well as the inter-ribbon space. Evacuation of [Co(3)(DPyP)(3)] x 4DMF at 130 degrees C generates [Co(3)(DPyP)(3)] that retains crystallinity, as shown by its powder X-ray diffraction pattern, which is consistent with that of [Co(3)(DPyP)(3)] x 4DMF.
引用本文（GB/T 7714）
Long Pan, Xiao‐Ying Huang, Hoa-Loan N. Phan, 等. 1-D Infinite Array of Metalloporphyrin Cages[J]. Inorganic Chemistry, 2004.
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