SYNTHESIS, CHARACTERIZATION OF CHIRAL POLY（ESTER AMIDE）S DERIVED FROM L-ISOLEUCINE
摘要
A series of new optically active aromatic poly(ester amide)s containing a chiral group in the side chain prepared from the p-toluenesulfonic acid salt of o,o'-bis(leucyl)-hexanediol (TS-+LHD+TS-) and p-phthaloyl chloride and styrene-2,5-dicarbonyl chloride styrene have been synthesized by interfacial polymerization. The structure of the monomer is elucidated by FT-IR and elemental analysis. The thermal properties of the polymers were studied by DSC and TGA. The chiroptical properties of the above polymer have also been studied by circular dichroism (CD) spectroscopy. Results indicated that these polymers form helical structures.
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范星河, Jing-lunZhou, Xiao-fangChen, 等. SYNTHESIS, CHARACTERIZATION OF CHIRAL POLY（ESTER AMIDE）S DERIVED FROM L-ISOLEUCINE[J]. Acta Scientiarum Naturalium Universitatis Sunyatseni, 2004.
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