Nanoscale Tail Aggregation in Ionic Liquids: Roles of Electrostatic and van der Waals Interactions
摘要
Nanoscale spatial heterogeneity in ionic liquids is formed by the aggregation of cationic tail groups.Theelectrostatic interactions between polar groups and the collective van der WaaJs interactions between nonpolar tail groupsboth contribute to the formation of tail domains,but the degrees of their contributions were unknown.In this work,byapplying a strong external electric field to effectively overpower the electrostatic interactions between polar groups,wehave determined that the tail aggregation is majorly attributed to the electrostatic interactions and the van der WaaJsinteractions only have minor influence on the spatial heterogeneity phenomenon of ionic liquids.
引用本文(GB/T 7714)
赵海清, 石锐, 王延颋. Nanoscale Tail Aggregation in Ionic Liquids: Roles of Electrostatic and van der Waals Interactions[J]. 理论物理通讯:英文版, 2011.
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