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Synthesis and Crystal Structure of Zinc Complex [Zn（bipy）3][Zn（SCN）4]

Xiang He、卢灿忠、张全争

2005结构化学Chemistry被引 1

摘要

The hydrothermal reaction of thiocyanate, 2,2'-bipyridine and ZnⅡ in basified aqueous solutions gave rise to complex [Zn(bipy)3][Zn(SCN)4] 1 (C34H24N1oS4Zn2) which was characterized by X-ray diffraction analysis. Crystal data for 1: monoclinic, space group P21/n, Mr= 831.61, Z= 4, a = 15.920(3), b = 13.5201(17), c = 17.362(3) (A), β= 99.467(9)°, V= 3686.1(10) (A)3, Dc= 1.499 g/cm3, μ = 1.568 mm-1, F(000) = 1688, R = 0.0586 and wR = 0.1354 for 5604 observed reflections (I ＞ 2σ(I)). The photoluminescence spectrum for the title compound has also been studied.

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