Mechanism of Photo-Fenton Degradation of Ethanol and PVA
摘要
Contrast degradation experiments between ethanol and polyvinyl alcohol (PVA) were conducted during H2O2, UV/H2O2, Fenton, and Photo-Fenton processes in this study. UV/VIS spectra showed: that complexes between Fe(Ⅲ) and organics were easily formed and degraded within reaction time. Compared with.the degradation of complex, hydroxyl radicals acted weakly in Fenton or Photo-Fenton process. Hydroxyl radicals involved in Photo-Fenton process were deemed to be generated from the split decomposition of H202, photolysis of Feaq^3+, and degradation of hydrated Fe(IV)-complex but not traditional Fenton reaction. Experimental evidence to support this point was presented in this paper.
引用本文(GB/T 7714)
雷乐成, 沈学优, 何锋. Mechanism of Photo-Fenton Degradation of Ethanol and PVA[J]. Acta Scientiarum Naturalium Universitatis Sunyatseni, 2003.
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