一种含硝基-NNO-氧化偶氮基新型含能材料的合成与表征
摘要
A novel energetic compound, N , N′ -dinitro- N , N′ -bis methylenediamine, was synthesized using 3-amino-4-( t -Bu- NNO -azoxy)furazan as starting material. And its structure was characterized by nuclear magnetic resonance ( 1 H NMR and 13 C NMR), infrared (IR) spectroscopy, elemental analysis and mass spectrometry, and its backbone was also confirmed by the X-ray structure study of the key intermediate. The detonation performance was calculated by VLW equation of state. Results show density is 1.94 g·cm -3 , detonation velocity 9502.52 m·s -1 , detonation pressure 41.79 GPa and enthalpy of formation 1007.67 kJ·mol -1 , indicating it is a competitive energetic materials.
引用本文（GB/T 7714）
Li Hui, 赵凤起, 于倩倩, 等. 一种含硝基-NNO-氧化偶氮基新型含能材料的合成与表征[J]. 未知来源, 2014.
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