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Calculation of Thermodynamic Parameters for Freundlich and Temkin Isotherm Models

ZhangzengqiangZhangyiping

1999Acta Scientiarum Naturalium Universitatis SunyatseniPhysics and Astronomy被引 1

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摘要

Derivation of the Freundlich and Temkin isotherm models from the kinetic adsorption/desorption equations was carried out to calculate their thermodynamic equilibrium constants.The calculation formulase of three thermodynamic parameters,the standard molar Gibbs free energy change,the standard molar enthalpy change and the standard molar entropy change,of isothermal adsorption processes for Freundlich and Temkin isotherm models were deduced according to the relationship between the thermodynamic equilibrium constants and the temperature.

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Zhangzengqiang, Zhangyiping. Calculation of Thermodynamic Parameters for Freundlich and Temkin Isotherm Models[J]. Acta Scientiarum Naturalium Universitatis Sunyatseni, 1999.

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