First Efficient Synthesis of 7-Epi-14-isocyano-isodauc-5-ene from a -(-)-Santonin
摘要
The natural products containing isodaucane skeleton 1 belonged to a rare kind of sesqiterpenes.1 In recent years, investigation on this kind sesquiterpenes have been attracting the interest of chemists, because some isodaucane sesquiterpenes isolated from the medical plants have been shown important bioactivities.2 The main synthetic challenge of isodaucane natural products resided in the introduction of syn-C1-methyl and C8-isopropyl groups. Although some approaches to synthesize isodaucane have been reported to date,3 they needed several steps to construct the cyclopentane unit bearing syn-methyl and isopropyl groups.
引用本文（GB/T 7714）
Li, Derun. First Efficient Synthesis of 7-Epi-14-isocyano-isodauc-5-ene from a -(-)-Santonin[J]. Acta Scientiarum Naturalium Universitatis Sunyatseni, 2001.
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